Classic spectra: Ruby — chromium doublet  ·  Almandine — Fe trio  ·  Zircon — 653.5 nm  ·  Peridot — Fe triplet  ·  Diamond (Cape) — 415 nm

A handheld spectroscope — diffraction-grating or prism — spreads the light returned by a gemstone into its visible spectrum and reveals which wavelengths the stone absorbs. Chromophore elements produce absorption patterns that act as fingerprints: chromium draws sharp lines in the red, iron cuts broad bands through the green and blue, rare-earth elements print fine line groups. For some separations the spectroscope is the fastest instrument on the bench — ruby vs. red garnet, or a Cape-series diamond vs. its simulants.

Reading a spectrum takes practice. Use strong, cool illumination (transmitted for transparent stones, reflected for opaque), keep the stone close to the slit, and let your eyes adapt. Note the positions of sharp lines first, then broad bands, working from the red end toward the violet. Ruby's chromium doublet is the classic example: 694.2 nm and 692.8 nm lines in the deep red, while almandine garnet shows its three-band iron signature across the yellow-green — two red stones, two unmistakably different spectra.

The chart below lists every recorded line and band per species with wavelength, cause where known, and relative strength. Species listed with no diagnostic absorption genuinely show none with a basic instrument — a blank spectrum on a strongly colored stone is itself a data point worth recording. Spectra pair naturally with the fluorescence chart: both read the same trace-element chemistry by different means.

Studying for the GIA or FGA practical? GemID drills spectrum reading alongside RI, SG, and UV response and runs timed mock exams built around the real exam formats.

Practice exams →
Gem Absorption Spectrum (visible, nm)
Zircon
  • 653.5 nm — Diagnostic zircon line (strong; the most distinctive zircon band, visible in most high-type specimens)
  • 659 nm — Zircon line (moderate; closely spaced with 653.5nm; together form a distinctive pair)
  • 621 nm — Zircon absorption line (moderate)
  • 615 nm — Zircon absorption line (moderate)
  • 589 nm — Zircon line (weak to moderate)
  • 562 nm — Zircon line (weak; part of the characteristic 'staircase' spectrum)
  • 537 nm — Zircon line (weak)
  • 516 nm — Zircon line (weak; staircase pattern continues)
Alexandrite
  • 680.3 nm — Cr³⁺ doublet (strong, diagnostic; the narrower line of the alexandrite doublet)
  • 678.5 nm — Cr³⁺ doublet companion (strong; broader companion line)
  • 665 nm — Cr absorption band (moderate)
  • 645 nm — Cr absorption band shoulder (moderate)
  • 580–620 nm — Broad absorption in orange region causing red/green color change
Iolite
  • 645 nm — Fe²⁺ band (strong; primary absorption in blue/violet iolite)
  • 593 nm — Fe²⁺ band (strong; diagnostic for iolite)
  • 585 nm — Fe²⁺ band (strong; part of diagnostic iron band group)
  • 535 nm — Fe²⁺ band (moderate; mid-spectrum iron absorption)
  • 492 nm — Fe²⁺ band (moderate)
Ruby
  • 694.2 nm — Cr³⁺ fluorescence line (strong, diagnostic; the stronger line of the ruby doublet; also visible as emission in fluorescence)
  • 692.8 nm — Cr³⁺ fluorescence line (strong; paired line of the diagnostic doublet)
  • 659 nm — Cr³⁺ absorption band (moderate; internal absorption in the red region)
  • 620 nm — Cr³⁺ broad absorption region (strong; part of broad green/yellow-green absorption band)
  • 476 nm — Cr³⁺ band (strong; part of broad blue-violet absorption causing complementary red color)
Spessartite Garnet
  • 432 nm — Mn²⁺ absorption band (strong; primary diagnostic band, most prominent in spessartite)
  • 420 nm — Mn²⁺ band (strong; short wavelength manganese band)
  • 412 nm — Mn²⁺ band (moderate; part of distinctive blue-violet Mn absorption group)
  • 504 nm — Fe²⁺ band (moderate; if Fe-bearing spessartite; pyrope-spessartite solid solution)
  • 520 nm — Fe²⁺ band (moderate; secondary iron band)
Spinel
  • 685 nm — Cr³⁺ doublet (strong, red/pink natural spinel)
  • 684 nm — Cr³⁺ doublet companion (strong, red/pink natural spinel)
  • 533 nm — Cobalt band (strong, diagnostic for synthetic cobalt blue spinel)
  • 580 nm — Cobalt band (strong, diagnostic for synthetic cobalt blue spinel)
  • 619 nm — Cobalt band (strong, diagnostic for synthetic cobalt blue spinel)
Almandine Garnet
  • 504 nm — Fe²⁺ band (strong, primary; most diagnostic band of the almandine trio)
  • 520 nm — Fe²⁺ band (strong; central band of the diagnostic yellow-green trio)
  • 573 nm — Fe²⁺ band (strong; third band completing the diagnostic trio)
  • 527 nm — Fe²⁺ secondary band (moderate)
Cubic Zirconia
  • Colorless CZ: no diagnostic absorption bands in the visible spectrum
  • Erbium-doped CZ: 518 nm and 524 nm — sharp doublet absorption lines in the green (strong; rare-earth Er³⁺); additional lines in violet, blue, and red
  • Holmium-doped CZ: ~540 nm — narrow absorption in the green (strong; rare-earth Ho³⁺)
  • Neodymium+erbium-doped CZ (tanzanite simulant): ~485–490 nm, ~520–525 nm, ~650 nm (broad group) — rare-earth absorption complex
Demantoid Garnet
  • 701 nm — Fe³⁺ band (strong; primary iron band for andradite/demantoid garnet)
  • 640 nm — Cr³⁺ band (moderate; chromium absorption in Cr-rich specimens)
  • 620 nm — Fe³⁺ band (moderate)
  • 443 nm — Fe²⁺ band (strong; characteristic blue-violet absorption band for demantoid/andradite garnet)
Emerald
  • 683 nm — Cr³⁺ doublet line (strong, diagnostic; primary line of emerald's chromium doublet)
  • 680 nm — Cr³⁺ doublet companion (strong; paired with 683nm line, diagnostic for chromium coloration)
  • 477 nm — Cr³⁺ broad absorption band (strong; causes absorption of violet-blue light)
  • 427 nm — Cr³⁺ band (moderate; short wavelength chromium band)
Pink Diamond
  • N3 415 nm
  • H3 503 nm
  • NV 575 nm
  • NV 637 nm
Tsavorite Garnet
  • 438 nm — V³⁺ broad absorption band (strong; primary vanadium band causing absorption of violet and transmission of green; diagnostic for vanadium-colored tsavorite)
  • 610 nm — V³⁺ absorption band (moderate; secondary vanadium band in orange-red region; part of the diagnostic V³⁺ absorption pair with 438 nm)
  • 630 nm — Cr³⁺ absorption line (moderate; chromium doublet band present in high-Cr tsavorites; forms pair with ~690 nm band)
  • 690 nm — Cr³⁺ absorption line (moderate; red-region chromium band present in Cr-bearing tsavorites; note: 701 nm is an Fe³⁺ band characteristic of andradite/demantoid and does NOT occur in tsavorite)
Yellow Diamond
  • N3 415 nm
  • Cape 452 nm
  • Cape 465 nm
  • H3 503 nm
Aquamarine
  • 537 nm — Fe²⁺ band (strong; primary diagnostic iron band for aquamarine)
  • 456 nm — Fe²⁺ band (moderate; iron absorption in violet-blue region)
  • 427 nm — Fe²⁺ band (weak to moderate; short wavelength iron band)
Brown Diamond
  • N3 415 nm
  • H3 503 nm
  • GR1 741 nm
Chrome Diopside
  • 690 nm — Cr³⁺ doublet line (strong; primary diagnostic chromium band for chrome diopside)
  • 686 nm — Cr³⁺ doublet companion (strong; paired with 690nm)
  • 506 nm — Fe²⁺ band (moderate; iron absorption also present in diopside)
Chrome Tourmaline
  • 637 nm — Cr³⁺ line (strong; primary diagnostic chromium line in chrome tourmaline)
  • 620 nm — Cr³⁺ band (moderate; secondary chromium band)
  • 478 nm — Cr³⁺ broad absorption (strong; blue-violet chromium absorption region)
Color-Change Sapphire
  • 450 nm — Fe²⁺/Fe³⁺ iron band (moderate; same as blue sapphire component)
  • 693 nm — Cr³⁺ line (weak to moderate; responsible for red/purple component in incandescent light)
  • 460 nm — Fe²⁺ iron band (moderate; contributes to blue component)
Diaspore
  • 453 nm — Mn³⁺ absorption band (strong; responsible for the color-change effect in diaspore)
  • 584 nm — Mn³⁺ band (moderate)
  • 550 nm — Mn/Fe broad absorption (moderate)
Enstatite
  • 506 nm — Fe²⁺ sharp diagnostic line (strong; characteristic of enstatite; most reliably seen in brownish/yellowish-green material)
  • 427 nm, 546 nm — Fe²⁺ weaker bands (visible in iron-bearing specimens)
  • 645 nm, 655 nm, 684 nm — Cr³⁺ bands (present only in chromium-bearing green enstatite; Cr³⁺ photoluminescence doublet at ~681–686 nm may also be seen)
Heliodor
  • 537 nm — Fe²⁺ band (strong; primary diagnostic iron band, same as aquamarine but typically stronger in heliodor)
  • 456 nm — Fe²⁺ band (moderate)
  • 427 nm — Fe²⁺ band (weak)
Hessonite Garnet
  • 432 nm — Mn²⁺ absorption band (moderate; iron-manganese grossular variety)
  • 410 nm — Fe³⁺ band (weak to moderate; hessonite contains Fe-Mn in solid solution)
  • 407 nm — Fe³⁺ band (weak)
Hiddenite
  • 686 nm — Cr³⁺ line (strong; primary chromium line in hiddenite/spodumene)
  • 669 nm — Cr³⁺ companion line (strong)
  • 646 nm — Cr³⁺ band (moderate)
Indicolite
  • 498 nm — Fe²⁺ band (strong; primary iron band in blue tourmaline)
  • 455 nm — Fe²⁺ band (moderate)
  • 640 nm — Fe²⁺ band (moderate; in deeply colored indicolite)
Kunzite
  • 553 nm — Mn³⁺ absorption band (moderate; primary diagnostic band for kunzite/spodumene)
  • 540 nm — Mn³⁺ band (moderate; paired with 553nm gives diagnostic doublet)
  • 433 nm — Mn absorption shoulder (weak)
Low-Type Zircon
  • 653.5 nm — Zircon line (weak to absent; low-type/metamict zircon shows fewer/weaker lines than high-type due to radiation damage)
  • 659 nm — Zircon line (weak; may be absent in fully metamict specimens)
  • Note — Lines progressively weaker as metamictization increases; fully metamict specimens may show no lines
Peridot
  • 493 nm — Fe²⁺ band (strong; the strongest and most visible of the peridot iron trio)
  • 473 nm — Fe²⁺ band (strong; second band of the diagnostic three-fingered absorption)
  • 453 nm — Fe²⁺ band (moderate; third band completing the diagnostic trio in the blue-violet region)
Pink Sapphire
  • 694 nm — Cr³⁺ line (moderate to strong; weaker than ruby; present in pink/red sapphire with Cr coloring)
  • 692 nm — Cr³⁺ companion line (moderate; paired with 694nm)
  • 476 nm — Cr³⁺ broad absorption (moderate; same as ruby but weaker at lower Cr concentrations)
Pyrope Garnet
  • 505 nm — Fe²⁺ band (moderate; weaker than almandine; primary band of pyrope iron trio)
  • 527 nm — Fe²⁺ band (moderate; central band)
  • 575 nm — Fe²⁺ band (moderate; third band; trio less pronounced than almandine)
Rhodolite Garnet
  • 505 nm — Fe²⁺ band (moderate; pyrope-almandine solid solution shows Fe bands)
  • 520 nm — Fe²⁺ band (moderate; weaker than pure almandine)
  • 573 nm — Fe²⁺ band (moderate; less pronounced than almandine trio)
Sapphire
  • 450 nm — Fe²⁺/Fe³⁺ iron band (strong, primary diagnostic for blue sapphire)
  • 460 nm — Iron band Fe²⁺ (moderate)
  • 471 nm — Iron band (moderate, part of diagnostic iron trio)
Sinhalite
  • 452 nm
  • 475 nm
  • 493 nm
Sphalerite
  • Fe²⁺ crystal-field band near 669–671 nm in red region (strong; clearly visible in hand spectroscope — diagnostic for sphalerite)
  • Fe²⁺ crystal-field band near 698–702 nm in deep red region (strong; part of the diagnostic triplet)
  • Fe²⁺ crystal-field band near 732–743 nm in deep red/near-infrared region (strong; third member of the Fe²⁺ triplet — note: attributed to Fe²⁺, not Cd²⁺ as older literature stated)
Sphene
  • 586 nm — Fe³⁺ band (strong; primary diagnostic iron band for sphene/titanite)
  • 532 nm — Fe³⁺ band (moderate)
  • 497 nm — Fe³⁺ band (moderate; part of the distinctive sphene iron absorption group)
Star Ruby
  • 694.2 nm — Cr³⁺ fluorescence line (strong; same as ruby; primary doublet line)
  • 692.8 nm — Cr³⁺ fluorescence line (strong; paired doublet line)
  • 476 nm — Cr³⁺ broad absorption (strong; blue-violet region absorption same as ruby)
Synthetic Spinel
  • Co²⁺ absorption band near 540–545 nm in green region (strong; part of cobalt triplet — diagnostic for cobalt-coloured synthetic spinel)
  • Co²⁺ absorption band near 580 nm in yellow-green region (strong; second member of diagnostic cobalt triplet)
  • Co²⁺ absorption band near 625–635 nm in orange-red region (strong; third member of diagnostic cobalt triplet — the triplet as a whole is essentially diagnostic for Co-doped synthetic spinel vs natural iron-blue spinel)
Tanzanite
  • 595 nm — V³⁺/Ti³⁺ absorption band (strong; vanadium/titanium causing the blue-violet color)
  • 528 nm — V³⁺ band (moderate; vanadium absorption in green-yellow region)
  • 455 nm — V³⁺ band (moderate; short wavelength vanadium band)
Turquoise
  • Cu²⁺ absorption band near 432 nm in violet-blue region (strong; diagnostic — visible in hand spectroscope; most reliable hand-instrument test for copper content)
  • Cu²⁺ absorption band near 460 nm in blue-violet region (weak; secondary band, sometimes visible as shoulder on the 432 nm feature)
  • Fe³⁺ absorption near 689 nm in red region (present in iron-bearing specimens only; absent in pure Cu turquoise — useful to distinguish greenish Fe-rich material from blue Cu-rich material)
Amazonite
  • Broad absorption band ~625–643 nm (blue color variety, Pb⁺ color center)
  • Broad absorption band ~720–740 nm (green color variety, O⁻–Pb⁺ color center)
Amethyst
  • 550 nm — Fe³⁺ broad absorption band (moderate; responsible for purple color in combination with color centers)
  • 530 nm — Absorption shoulder (weak to moderate)
Andalusite
  • 553 nm — Mn³⁺ absorption band (moderate; responsible for green pleochroic color)
  • 550 nm — Broad Mn absorption region (strongest in green direction)
Apatite
  • 512 nm — Rare earth (Dy³⁺) band (moderate; present in some yellow-green apatite)
  • 491 nm — Rare earth band (weak; Pr³⁺ in some specimens)
Benitoite
  • 435 nm — Absorption band (moderate; related to Ti content in benitoite)
  • 412 nm — Absorption band (weak)
Blue Diamond
  • Broad boron-related absorption tail extending from near-infrared into red visible region (responsible for blue colour in Type IIb; diffuse — no sharp discrete line visible in hand spectroscope)
  • No sharp diagnostic lines in visible range — FTIR (2800 cm⁻¹ region) is the definitive boron test; hand spectroscope is not diagnostic for blue diamonds
Cassiterite
  • Strong absorption in the near-UV to violet region, ~350–400 nm (shifts by color variety)
  • Brownish-pink varieties show broad band centered ~490 nm
Cat's Eye Chrysoberyl
  • 444 nm — Fe³⁺ absorption band (strong; visible in hand spectroscope — diagnostic for chrysoberyl vs quartz cat's-eye)
  • 484–505 nm — Fe³⁺ weaker band region (sometimes visible as a diffuse absorption edge in blue-green)
Chrysoprase
  • Broad Ni²⁺ absorption centered near 630–660 nm in orange-red region (responsible for green colour; no sharp lines — visible as diffuse red-end suppression in hand spectroscope)
  • Secondary Ni²⁺ absorption near 380–400 nm in UV-violet region (contributes to overall colour balance)
Citrine
  • 432 nm — Fe³⁺ band (weak; present in natural citrine; distinguishes from glass simulants)
  • 420 nm — Fe³⁺ band shoulder (weak; often faint in heat-treated amethyst/citrine)
Clinohumite
  • ~450 nm — general absorption cut-off in the violet (strong; Fe²⁺ in octahedral sites)
  • ~540 nm — broad absorption band in the green-yellow region (moderate; Fe²⁺, causes yellow-orange body color)
Grandidierite
  • 480–490 nm — Fe²⁺ absorption doublet (weak to moderate; visible in hand spectroscope in face-up orientation — useful diagnostic for this rare gem)
  • Broad Fe²⁺/Fe³⁺ absorption in orange-red region contributing to strong trichroism (dark blue-green / blue / near-colourless)
Green Tourmaline
  • 496 nm FE
  • 611 nm FE
Grossular Garnet
  • 407 nm — Fe³⁺ absorption band (weak; present in Fe-bearing grossular varieties)
  • 430 nm — Fe³⁺ broad absorption (weak to moderate; varies with iron content)
Hackmanite
  • ~540 nm — F-centre / colour-centre absorption (moderate; responsible for pink-to-purple photochromic colour when UV-activated; present only after UV exposure — fades in daylight)
  • No diagnostic bands visible in hand spectroscope on untreated/unactivated material
Jadeite
  • 437 nm — Fe³⁺ band (strong; diagnostic for jadeite; most visible in lavender/white jadeite)
  • 630–690 nm — Cr³⁺ bands (strong in imperial green jadeite; chromium doublet-like absorption producing vivid green; absent in Fe-colored greens)
Kornerupine
  • 446 nm — Fe²⁺/Cr³⁺ broad absorption (moderate; chromium-bearing green kornerupine)
  • 540 nm — Broad absorption region (moderate; Fe/Cr giving green color in some specimens)
Kyanite
  • 447 nm — Fe²⁺ band (moderate; diagnostic iron band most visible in blue kyanite)
  • 433 nm — Fe²⁺ band (weak)
Lapis Lazuli
  • Broad S₃·⁻ radical absorption centered near 600 nm in orange region (responsible for blue colour — diagnostic for lazurite; visible as general orange suppression in hand spectroscope)
  • Weak secondary absorption near 400 nm in violet region (S₃·⁻ minor band; not always detectable in hand spectroscope)
Malachite
  • Broad Cu²⁺ absorption centered near 800 nm in near-infrared/deep red region (responsible for green colour; visible as strong red-end suppression in hand spectroscope — no discrete line)
  • Absorption cut-off below ~520 nm in blue-violet region (secondary Cu²⁺ band; contributes to green transmission window)
Moldavite
  • Broad Fe²⁺/Fe³⁺ diffuse absorption in blue-violet and near-infrared regions (no sharp lines; two vague bands sometimes noted in blue and orange regions with spectrophotometer — not reliably visible in hand spectroscope)
  • No diagnostic discrete lines detectable in hand spectroscope — RI (~1.48–1.50) and tektite surface texture are primary tests
Morganite
  • 572 nm — Mn³⁺ absorption band (strong; primary diagnostic band for morganite's pink color)
  • 540 nm — Mn³⁺ band (moderate; secondary manganese band)
Nephrite
  • Diffuse Fe²⁺ absorption near 430–450 nm in violet-blue region (present in dark green nephrite; weak and broad — visible as blue-end suppression rather than a discrete line)
  • Broad Fe²⁺/Fe³⁺ absorption in the 600–730 nm orange-red region (responsible in part for green body colour; not a discrete line — most visible as general red-end suppression)
Padparadscha Sapphire
  • 450 nm — Fe²⁺ band (moderate; iron contributing to orange component)
  • 693 nm — Cr³⁺ line (weak; chromium contributing to pink component of padparadscha color)
Paraiba Tourmaline
  • 700 nm+ — Cu²⁺ broad absorption tail (strong; copper causes the neon blue-green color; extends into NIR)
  • 560 nm — Mn³⁺ broad absorption (strong; manganese absorption band in yellow-green region; reduced or absent after heat treatment)
Prasiolite
  • ~720 nm — broad, weak absorption band in the red (Fe²⁺ intervalence charge transfer; responsible for green hue in heat-treated material)
  • ~550 nm — faint Fe³⁺ absorption band (weak; may be present in natural material)
Rhodochrosite
  • Mn²⁺ absorption near 410–425 nm in violet region (Fe²⁺/Mn²⁺ crystal-field band; visible in hand spectroscope in deeply coloured specimens)
  • Mn²⁺ absorption near 450–460 nm in blue-violet region (second crystal-field band; may appear as broad absorption shoulder)
Rhodonite
  • Mn²⁺ absorption near 410 nm in violet region (crystal-field band; analogous to rhodochrosite)
  • Mn²⁺ absorption near 503 nm in blue-green region (second Mn²⁺ band; visible in deeply coloured specimens as a diffuse band)
Rubellite
  • 524 nm — Mn³⁺ absorption band (strong; primary diagnostic band for rubellite's red-pink color)
  • 453 nm — Mn³⁺ band (moderate; short wavelength manganese band)
Scapolite
  • 663 nm — Mn²⁺ band (moderate; present in purple/violet scapolite; manganese coloration)
  • 652 nm — Mn²⁺ band (moderate; paired with 663nm)
Serpentine
  • ~450 nm — weak, broad absorption band in the blue-violet (Fe³⁺ from oxidized structural Fe²⁺)
  • ~570 nm — weak, broad absorption band in the yellow-green (Fe³⁺; contributes to green body color)
Star Diopside
  • 505 nm — Fe²⁺/Fe³⁺ absorption band (moderate; iron absorption in diopside)
  • 508 nm — Fe²⁺ band (moderate; diagnostic for iron-bearing diopside)
Star Sapphire
  • 450 nm — Fe²⁺/Fe³⁺ iron band (moderate; same as blue sapphire; diagnostic for blue star sapphire)
  • 460 nm — Fe²⁺ band (moderate)
Synthetic Color-Change Corundum
  • 693 nm — Cr³⁺ line (strong; vanadium and chromium dopants used to create blue-to-red color change)
  • 450 nm — Fe²⁺/V³⁺ band (strong; causes absorption of visible blue-green in combination with Cr/V)
Taaffeite
  • Iron-bearing specimens may show absorption similar to iron-bearing spinel (broad Fe²⁺ band 400–590 nm)
  • Chromium-rich specimens show absorption band ~550 nm
Thulite
  • Mn³⁺ absorption near 455 nm in violet-blue region (crystal-field band; visible in hand spectroscope in deeply coloured specimens)
  • Mn³⁺ absorption near 560–580 nm in yellow-green region (second Mn³⁺ band; responsible for pink colour by subtracting green from white light)
Variscite
  • Cr³⁺ absorption doublet with bands near 645 nm and 690 nm in orange-red region (visible in hand spectroscope — similar pattern to emerald; supports Cr³⁺ as chromophore)
  • Broad Cr³⁺ absorption near 430–450 nm in violet region (responsible for absorbing violet, contributing to green transmission)
Watermelon Tourmaline
  • Variable FE in green zone
  • MN in pink zone
Yellow Sapphire
  • 450 nm — Fe²⁺ band (weak to moderate; Fe-colored yellow sapphire may show this band; absent in Be-diffused material)
  • 460 nm — Fe²⁺ band (weak; secondary iron band)
Ametrine
  • Broad absorption band centered ~540 nm (amethyst zones, Fe³⁺/Fe⁴⁺ charge transfer)
Aventurine
  • Chromium (Cr³⁺) absorption from fuchsite inclusions: bands ~450 nm and ~600–680 nm
Bloodstone
  • Broad Fe absorption; diffuse bands in the red ~630–670 nm region from iron oxide/hematite inclusions
Carnelian
  • Broad diffuse iron absorption bands centered near 580 nm, 610 nm, 630 nm, 640 nm, and 665 nm
Chrysoberyl
  • 444 nm — Fe³⁺ band (moderate; most visible in yellow-green chrysoberyl; iron absorption in blue-violet region)
Chrysocolla
  • Broad Cu²⁺ absorption centered near 700–800 nm in orange-red region (responsible for blue-green colour transmission; visible as general red suppression rather than a discrete line)
Cinnabar
  • ~600 nm — strong absorption edge; blue-violet and green regions essentially cut off (band-gap absorption in HgS causes intense red/vermilion color)
Color-Change Garnet
  • Three broad bands across orange-yellow-green — garnet trio
Cuprite
  • ~450–530 nm — broad, strong absorption across blue to green-yellow (band-gap and charge-transfer absorption in Cu₂O; causes deep red color)
Diamond
  • Sharp line in the violet (~415nm) — Cape diamond line
Hauyne
  • Broad S₃·⁻ radical absorption centered near 595–620 nm in orange region (responsible for intense blue colour; diffuse — visible as general orange-red suppression in hand spectroscope rather than a discrete line)
Labradorite
  • ~418 nm and ~448 nm — two weak, diffuse absorption bands in the violet-blue (weak; Fe³⁺ in tetrahedral Si/Al sites; often too faint for hand spectroscope)
Larimar
  • Broad absorption centered near 630 nm in orange region (attributed to Cu²⁺ and/or Fe²⁺–Fe³⁺ intervalence charge transfer — responsible for blue-green colour; no sharp lines visible in hand spectroscope)
Malaya / Umbalite Garnet
  • Broad bands in the green (~524nm) and blue-violet (~453nm) — manganese
Moissanite
  • 419 nm — Diagnostic absorption band for synthetic moissanite (SiC)
Prehnite
  • ~438 nm — weak absorption band in the violet-blue (Fe³⁺ in octahedral Al sites; causes pale green color)
Red Beryl
  • MN absorption bands
Rose Quartz
  • ~500 nm — weak, broad absorption band (Fe-Ti intervalence charge transfer in fibrous inclusions; causes pink color)
Sodalite
  • ~675 nm — step-shaped absorption in the red (S²⁻/S³⁻ sulfide cluster electronic transition; contributes to royal blue color)
Star Garnet
  • Three broad bands across orange-yellow-green — garnet trio
Sugilite
  • Broad Mn³⁺ absorption envelope centered near 560 nm spanning approximately 500–700 nm (responsible for violet-purple colour; visible in hand spectroscope as broad green-yellow suppression)
Sunstone
  • ~560–590 nm — broad absorption band (localized surface plasmon resonance of copper nanoparticle inclusions; causes red-orange to green colors in Oregon sunstone)
Tourmaline
  • Variable by color — Fe²⁺ bands in green/blue varieties; Mn³⁺ bands in pink/red; Cr³⁺ bands in chrome tourmaline; Cu²⁺ bands in Paraiba
White Sapphire
  • No strong diagnostic bands — white/colorless sapphire typically shows clean spectrum (no Fe or Cr color centers in colorless corundum)
YAG
  • No diagnostic absorption bands in colorless YAG — clean featureless spectrum (undoped YAG has no chromophores)
  • Colored YAG (doped): Er³⁺ at 450nm+, Nd³⁺ at 578nm, Cr³⁺ at 689nm depending on dopant used
Agate
  • No diagnostic absorption bands in the visible spectrum
Amber
  • No diagnostic absorption bands in the visible spectrum
Black Opal
  • No diagnostic absorption bands in the visible spectrum
Black Spinel
  • No diagnostic visible bands — black spinel shows general absorption; Fe-Ti charge transfer causes near-complete absorption throughout visible spectrum in opaque specimens
Chalcedony
  • No diagnostic absorption bands in the visible spectrum
Charoite
  • No diagnostic absorption bands in the visible spectrum
Coral
  • No diagnostic absorption bands in the visible spectrum
Danburite
  • No diagnostic absorption bands — danburite shows a clean featureless spectrum; colorless to pale yellow specimens are essentially transparent across the visible range
Fire Opal
  • No diagnostic absorption bands in the visible spectrum
Fluorite
  • No diagnostic absorption bands — spectrum generally clean (fluorite is typically featureless in the visible range)
Goshenite
  • No diagnostic absorption bands in the visible spectrum
Hawk's Eye
  • No diagnostic absorption bands in the visible spectrum (opaque/chatoyant; residual Fe absorption from crocidolite/riebeckite fibers not resolvable in hand spectroscope)
Hematite
  • No diagnostic absorption bands visible in the visible spectrum with a hand spectroscope (opaque metallic material; broad Fe₂O₃ absorption throughout visible range)
Howlite
  • No diagnostic absorption bands in the visible spectrum
Ivory
  • No diagnostic absorption bands in the visible spectrum
Jet
  • No diagnostic absorption bands in the visible spectrum (opaque black organic material absorbs all visible wavelengths)
Moonstone
  • No diagnostic absorption bands in the visible spectrum
Obsidian
  • No diagnostic absorption bands in the visible spectrum
Onyx
  • No diagnostic absorption bands in the visible spectrum (opaque; black color from carbonized inclusions or dye treatment)
Opal
  • No diagnostic absorption bands in the visible spectrum
Pearl
  • No diagnostic absorption bands in the visible spectrum (hand spectroscope)
Phenakite
  • No diagnostic absorption bands in the visible spectrum
Pietersite
  • No diagnostic absorption bands in the visible spectrum (opaque/chatoyant; Fe absorption from hematite/goethite inclusions diffuse and not resolvable)
Rainbow Moonstone
  • No diagnostic absorption bands in the visible spectrum
Rock Crystal
  • No diagnostic absorption bands in the visible spectrum
Smoky Quartz
  • No diagnostic visible bands — spectrum featureless (color from Al/H color centers; no sharp spectroscope lines visible in standard gemological spectroscope)
Tiger's Eye
  • No diagnostic absorption bands in the visible spectrum (opaque/chatoyant; diffuse Fe³⁺/limonite absorption not resolvable into lines)
Topaz
  • No diagnostic absorption bands — spectrum generally featureless (most topaz colors arise from color centers or trace elements without sharp spectroscope absorption)

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Which gemstones have diagnostic absorption spectra?
101 of the 130 species in this chart have recorded absorption features, led by the chromium-colored stones (ruby, emerald, alexandrite), the iron-signature stones (almandine garnet, peridot, sapphire), and zircon with its distinctive 653.5 nm line.

What does the ruby spectrum look like in a spectroscope?
Ruby shows a chromium spectrum: the 694.2 nm / 692.8 nm doublet in the deep red, plus broad absorption through the green. Red garnets lack the doublet and show iron bands instead — the fastest ruby-vs-garnet separation on the bench.

What is the 415 nm line in diamond?
The 415 nm line (the "Cape line," from the N3 defect center) is a sharp absorption in the violet shown by Cape-series diamonds. Seeing it confirms natural Type Ia diamond — most simulants and most lab-grown diamonds do not show it.

All instrument charts: Refractive Index  ·  Specific Gravity  ·  Mohs Hardness  ·  Birefringence  ·  Fluorescence  ·  Pleochroism  ·  Optic Character  ·  Chelsea & Hanneman Filters  ·  Dispersion  ·  Magnetism

See also: Full Reference Database  ·  How to Identify a Gemstone  ·  Exam Study Guides

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